Protonated base

pKa

∆H˚

∆S˚

∆Cp˚

Ref

(CH3)3CN+H3

10.685

60,070

−3.1

15

[17]

(CH3)2(CH2OH)CN+H3

9.694

53,948

−4.9

−19

[18]

CH3(CH2OH)2CN+H3

8.797

49,794

−1.3

−45

[10] [18]

(CH2OH)3CN+H3

8.072

47,488

4.8

−78

[9] [19]

OHCH2CH2N+H3

9.498

50,543

−12.1

−4

[12]

(CH2OH)3N+H

8.075

47,614

5.1

−63

[17]

(CH2CH2OH)3N+H

7.762

33,472

−36.4

52

[21]

(CH2CH2OH)2N+H2

8.816

42,426

−28

49

[10]

(CH2OH)3CN+H(C2H4OH)2

6.483

28,238

−29.4

24

[11]

6.483

28,273

−29.3

36

This work