Protonated base | pKa | ∆H˚ | ∆S˚ | ∆Cp˚ | Ref |
(CH3)3CN+H3 | 10.685 | 60,070 | −3.1 | 15 | |
(CH3)2(CH2OH)CN+H3 | 9.694 | 53,948 | −4.9 | −19 | |
CH3(CH2OH)2CN+H3 | 8.797 | 49,794 | −1.3 | −45 | |
(CH2OH)3CN+H3 | 8.072 | 47,488 | 4.8 | −78 | |
OHCH2CH2N+H3 | 9.498 | 50,543 | −12.1 | −4 | |
(CH2OH)3N+H | 8.075 | 47,614 | 5.1 | −63 | |
(CH2CH2OH)3N+H | 7.762 | 33,472 | −36.4 | 52 | |
(CH2CH2OH)2N+H2 | 8.816 | 42,426 | −28 | 49 | |
(CH2OH)3CN+H(C2H4OH)2 | 6.483 | 28,238 | −29.4 | 24 | |
6.483 | 28,273 | −29.3 | 36 | This work |